07 Dec




















pottery is subjected in order to achieve its final character of permanence and rigidity in the body and of vitrification of the glaze with the development of colour. The tem- perature range in which chemical and physical changes may proceed in a clay body extends from atmospheric temperature to 1,850 C., at which point the most re- fractory clays are affected. At ordinary temperatures we have colloidal action, at 200 the changes induced by the so-called pre-heating treatment, at 440 to 500 dehydration has almost ceased, and plasticity is lost beyond recovery. According to Witt and Knote, A1 2 3 . 2Si0 2 . 2H 2 decomposes on dehydration into water, and the silicates A1 2 3 . Si0 2 and A1 2 3 . 3Si0 2 or some higher silicate, and not into the monosilicate and free silica as formerly sup- posed. Mellor states, however, that the endothermal change shown at 500 corresponds with the decomposition of kaolinite into free silica, free alumina and water. Pro- ceeding to higher temperatures the density decreases, but suddenly increases at 950, where an exothermic re- action obtains. Thence changes occur in clay bodies which are much the same in all, but take place at different tem- peratures according to the refractoriness of the body. But under sufficiently severe heat every body assumes a crystalline structure similar to the sillimanite in porce- lain. At still higher temperatures vitrification proceeds to a finish, accompanied by an increase in specific volume. The melting point of a body or glaze depends chiefly

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